碳酸钠是一种重要的无机化工原料,主要用于玻璃制品和陶瓷釉的生产,还广泛用于生活洗涤、酸类中和以及食品加工等。工业制碱法大致经历了如图所示的三个阶段。
![](http://tikupic.21cnjy.com/ct20241o/35/8d/358de1ffb1bae600cbc86e4b4e3b2652.png)
I.路布兰是开创化学工业的先驱者,路布兰制碱法是化工史上的一个里程碑。路布兰制碱法的原理如下:
①![](http://math.21cnjy.com/mml2svg?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmrow%3E%3Cmn%3E2%3C%2Fmn%3E%3Cmtext%3ENaCl%3C%2Fmtext%3E%3Cmo%3E%2B%3C%2Fmo%3E%3Cmsub%3E%3Cmtext%3EH%3C%2Fmtext%3E%3Cmn%3E2%3C%2Fmn%3E%3C%2Fmsub%3E%3Cmsub%3E%3Cmrow%3E%3Cmtext%3ESO%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmn%3E4%3C%2Fmn%3E%3C%2Fmsub%3E%3Cmtable%3E%3Cmtr%3E%3Cmtd%3E%3Cmrow%3E%3Cmunder+accentunder%3D%22false%22%3E%3Cmunder+accentunder%3D%22false%22%3E%3Cmi+mathvariant%3D%22normal%22%3E%CE%94%3C%2Fmi%3E%3Cmo+stretchy%3D%22true%22%3E_%3C%2Fmo%3E%3C%2Fmunder%3E%3Cmo+stretchy%3D%22true%22%3E_%3C%2Fmo%3E%3C%2Fmunder%3E%3C%2Fmrow%3E%3C%2Fmtd%3E%3C%2Fmtr%3E%3Cmtr%3E%3Cmtd%3E%3Cmrow%3E%3C%2Fmrow%3E%3C%2Fmtd%3E%3C%2Fmtr%3E%3C%2Fmtable%3E%3Cmsub%3E%3Cmrow%3E%3Cmtext%3ENa%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmn%3E2%3C%2Fmn%3E%3C%2Fmsub%3E%3Cmsub%3E%3Cmrow%3E%3Cmtext%3ESO%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmn%3E4%3C%2Fmn%3E%3C%2Fmsub%3E%3Cmo%3E%2B%3C%2Fmo%3E%3Cmn%3E2%3C%2Fmn%3E%3Cmtext%3EHCl%3C%2Fmtext%3E%3Cmo%3E%E2%86%91%3C%2Fmo%3E%3C%2Fmrow%3E%3C%2Fmath%3E)
②![](http://math.21cnjy.com/mml2svg?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmrow%3E%3Cmsub%3E%3Cmrow%3E%3Cmtext%3ENa%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmn%3E2%3C%2Fmn%3E%3C%2Fmsub%3E%3Cmsub%3E%3Cmrow%3E%3Cmtext%3ESO%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmn%3E4%3C%2Fmn%3E%3C%2Fmsub%3E%3Cmo%3E%2B%3C%2Fmo%3E%3Cmn%3E4%3C%2Fmn%3E%3Cmtext%3EC%3C%2Fmtext%3E%3Cmtable%3E%3Cmtr%3E%3Cmtd%3E%3Cmrow%3E%3Cmunder+accentunder%3D%22false%22%3E%3Cmunder+accentunder%3D%22false%22%3E%3Cmrow%3E%3Cmi+mathvariant%3D%22normal%22%3E%E9%AB%98%3C%2Fmi%3E%3Cmi+mathvariant%3D%22normal%22%3E%E6%B8%A9%3C%2Fmi%3E%3C%2Fmrow%3E%3Cmo+stretchy%3D%22true%22%3E_%3C%2Fmo%3E%3C%2Fmunder%3E%3Cmo+stretchy%3D%22true%22%3E_%3C%2Fmo%3E%3C%2Fmunder%3E%3C%2Fmrow%3E%3C%2Fmtd%3E%3C%2Fmtr%3E%3Cmtr%3E%3Cmtd%3E%3Cmrow%3E%3C%2Fmrow%3E%3C%2Fmtd%3E%3C%2Fmtr%3E%3C%2Fmtable%3E%3Cmsub%3E%3Cmrow%3E%3Cmtext%3ENa%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmn%3E2%3C%2Fmn%3E%3C%2Fmsub%3E%3Cmtext%3ES%3C%2Fmtext%3E%3Cmo%3E%2B%3C%2Fmo%3E%3Cmn%3E4%3C%2Fmn%3E%3Cmtext%3ECO%3C%2Fmtext%3E%3Cmo%3E%E2%86%91%3C%2Fmo%3E%3C%2Fmrow%3E%3C%2Fmath%3E)
③![](http://math.21cnjy.com/mml2svg?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmrow%3E%3Cmsub%3E%3Cmrow%3E%3Cmtext%3ENa%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmn%3E2%3C%2Fmn%3E%3C%2Fmsub%3E%3Cmtext%3ES%3C%2Fmtext%3E%3Cmo%3E%2B%3C%2Fmo%3E%3Cmsub%3E%3Cmrow%3E%3Cmtext%3ECaCO%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmn%3E3%3C%2Fmn%3E%3C%2Fmsub%3E%3Cmo%3E%3D%3C%2Fmo%3E%3Cmsub%3E%3Cmrow%3E%3Cmtext%3ENa%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmn%3E2%3C%2Fmn%3E%3C%2Fmsub%3E%3Cmsub%3E%3Cmrow%3E%3Cmtext%3ECO%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmn%3E3%3C%2Fmn%3E%3C%2Fmsub%3E%3Cmo%3E%2B%3C%2Fmo%3E%3Cmtext%3ECaS%3C%2Fmtext%3E%3C%2Fmrow%3E%3C%2Fmath%3E)
请回答下列问题:
(1)反应①属于{#blank#}1{#/blank#}(填四大基本反应类型),反应②中的氧化产物为{#blank#}2{#/blank#}(填化学式)。
(2)路布兰制碱法的缺点有{#blank#}3{#/blank#}(写出一点即可)。
II.1861年,比利时人欧内斯特·索尔维发明了以食盐、石灰石、氨气为原料制取碳酸钠的索尔维制碱法(又称氨碱法),其工业生产的简单流程如下图所示。
![](http://tikupic.21cnjy.com/ct20241o/50/ca/50ca7c9ab762c990b7c26a2e5d2a989a.png)
请回答下列问题:
(3)上述流程涉及的物质中,属于碱性氧化物的是{#blank#}4{#/blank#}(填化学式)。
(4)往饱和
溶液中持续通入
, 观察到的现象为{#blank#}5{#/blank#}。
III.1943年左右我国著名科学家侯德榜先生克服重重困难,把合成氨工业和氨碱法制碱工业结合起来,发明了联合制碱法,也被人们称为“侯氏制碱法”,该方法大大提高了原料的利用率,其流程如图所示。
![](http://tikupic.21cnjy.com/ct20241o/e9/3e/e93e61f774d445ac5c7f0508624a8ed8.png)
请回答下列问题:
(6)相比索尔维制碱法,侯氏制碱法的优点有{#blank#}8{#/blank#}(填标号)。
a.用等量的食盐可以生产更多的纯碱,同时得到氮肥氯化铵,NaCl的利用率高
b.不产生用途不大且难处理的
, 对环境更加友好
c.侯氏制碱法无须加热
d.侯氏制碱法中
可以循环使用,后续无须补充![](http://math.21cnjy.com/mml2svg?mml=%3Cmath+xmlns%3D%22http%3A%2F%2Fwww.w3.org%2F1998%2FMath%2FMathML%22%3E%3Cmrow%3E%3Cmsub%3E%3Cmrow%3E%3Cmtext%3ECO%3C%2Fmtext%3E%3C%2Fmrow%3E%3Cmn%3E2%3C%2Fmn%3E%3C%2Fmsub%3E%3C%2Fmrow%3E%3C%2Fmath%3E)