已知:P
4(g)+6Cl
2(g)=4PCl
3(g) ΔH=akJ·mol
-1 , P
4(g)+10Cl
2(g)=4PCl
5(g) ΔH=b kJ·mol
-1 , P
4具有正四面体结构(如图),PCl
5中P-Cl键的键能为c kJ·mol
-1 , PCl
3中P—Cl键的键能为1.2c kJ·mol
-1。下列叙述正确的是
A、P-P键的键能大于P-Cl键的键能
B、可求Cl2(g)+PCl3(g)=PCl5(s)的反应热ΔH
C、Cl-Cl键的键能为0.25(b﹣a+5.6c) kJ·mol-1
D、P-P键的键能为0.125(5a﹣3b +12c)kJ·mol-1